Elemental Selenium Or Tellurium Patents (Class 423/510)
  • Patent number: 4038376
    Abstract: A process for the recovery of selenium from a urethane solution containing selenium compounds which may be in the form of metallic selenium, inorganic selenium and/or organoselenium compounds which comprises contacting the selenium-containing urethane solution at suitable temperatures with a supported metal or a mixture of metals and/or metal oxide compounds, said metal selectively chosen from Group B metals, i.e., Group IB through VIIIB, metals of the Periodic Table and particularly supported copper and mixtures of copper and other metal oxide compounds of said group.
    Type: Grant
    Filed: August 12, 1975
    Date of Patent: July 26, 1977
    Assignee: Atlantic Richfield Company
    Inventors: John J. McCoy, John G. Zajacek
  • Patent number: 4026797
    Abstract: Selenium is removed from copper electrolytes by adding a substance selected from the group consisting of metals above copper in the electromotive series, excluding alkali metals, such as nickel powder, cobalt powder and iron powder. Sodium sulfide can also be used along with a subsequent addition of ferric sulfate. The amount of the reactive substance added should be sufficient to reduce the selenium content to below 2 ppm.
    Type: Grant
    Filed: April 19, 1976
    Date of Patent: May 31, 1977
    Assignee: Amax Inc.
    Inventors: Cvetko B. Nikolic, John M. Laferty
  • Patent number: 4009249
    Abstract: Red amorphous selenium is obtained by precipitating selenium from a solution of selenious acid in methanol or ethanol with hydrazine or a soluble salt thereof at a temperature between about -20.degree. C. and the freezing point of the solution. Furthermore, the stable red amorphous selenium may contain a halogen.
    Type: Grant
    Filed: January 16, 1976
    Date of Patent: February 22, 1977
    Assignee: Xerox Corporation
    Inventor: David A. Buckley
  • Patent number: 4007255
    Abstract: Red amorphous selenium is obtained by precipitating selenium from a solution of selenious acid in methanol or ethanol with hydrazine or a soluble salt thereof at a temperature between about -20.degree. C. and the freezing point of the solution. Further, the stable red amorphous may contain thallium which may then contain a halogen.
    Type: Grant
    Filed: January 16, 1976
    Date of Patent: February 8, 1977
    Assignee: Xerox Corporation
    Inventor: David A. Buckley
  • Patent number: 3994791
    Abstract: Process for preparation of a solid phase dispersion of photoconductive materials in an insulating binder matrix from a film forming insulating polymeric resin and an organo-selenium compound capable of undergoing selective decomposition in response to an appropriate stimulus; whereby, elemental selenium is extruded from said organo-selenium compound and deposited in the binder matrix. Because this extrusion/deposition of elemental selenium can be performed selectively, it is possible to prepare binder films having photoconductive image patterns which are suitable for use in range extended and conventional xerography.
    Type: Grant
    Filed: March 26, 1974
    Date of Patent: November 30, 1976
    Assignee: Xerox Corporation
    Inventors: Joseph Y. C. Chu, W. H. H. Gunther
  • Patent number: 3993815
    Abstract: There are provided curable anaerobic pressure sensitive adhesive stocks in the form of sheets and tapes in which the adhesive is contained between two differential release surfaces. This construction permits total pressure sensitive adhesive transfer to a substrate which is to be firmly secured to another substrate upon the exclusion of oxygen and initiation of cure of the anaerobic resin.The adhesive layer provided may be homogeneous or heterogeneous, and there may be contained within the adhesive layer a support layer.The release liner employed is preferably impervious to migration of contained compounds which serve as the accelerators for cure of the curable anaerobic resin.
    Type: Grant
    Filed: October 7, 1974
    Date of Patent: November 23, 1976
    Assignees: Avery Products Corporation, Loctite Corporation
    Inventors: Maurice Douek, Gustav A. Schmidt, Bernard M. Malofsky, Martin Hauser
  • Patent number: 3992511
    Abstract: A process for recovering pure selenium from metal substrates having a selenium coating thereon without impairment of the substrate for reuse which comprises substantially converting the selenium in said coating to a water-soluble selenocyanate by immersing the coated substrate in an aqueous solution of an alkali metal cyanide, removing the substrate from the resultant solution, treating the resultant solution with an acid to precipitate the selenium from the remaining liquid.
    Type: Grant
    Filed: April 14, 1972
    Date of Patent: November 16, 1976
    Assignee: Xerox Corporation
    Inventors: Kenneth A. Waehner, Anthony T. Giammarise
  • Patent number: 3973917
    Abstract: The present invention relates to a method and apparatus for purifying selenium or its alloys by precipitation. The method is characterized in that a smaller portion of a larger amount selenium or selenium alloy is kept at the respective transition temperature between solid and liquid phases while the remaining portion is maintained at a higher temperature for a time sufficiently long to allow a substantial concentration of foreign elements in the smaller portion.The apparatus is characterized in that it consists of a glass vessel having a height approximately 10 times its diameter, provided with temperature indicators governing devices controlling the heat supplied to electrical elements arranged around the vessel, it also being provided with a tightly-fitting hood and a gas evacuation device.
    Type: Grant
    Filed: July 30, 1973
    Date of Patent: August 10, 1976
    Assignee: Boliden Aktiebolag
    Inventor: Sten Tycho Henriksson
  • Patent number: 3969495
    Abstract: A thermochemical reaction cycle for the generation of hydrogen from water comprising the following sequence of reactions wherein M represents a metal and Z represents a metalloid selected from the arsenic-antimony-bismuth and selenium-tellurium subgroups of the periodic system:2MO + Z + SO.sub.2 .fwdarw. MZ + MSO.sub.4 (1)mz + h.sub.2 so.sub.4 .fwdarw. mso.sub.4 + h.sub.2 z (2)2mso.sub.4 .fwdarw. 2mo + so.sub.2 + so.sub.3 + 1/20.sub.2 (3)h.sub.2 z .fwdarw. z + h.sub.2 (4)h.sub.2 o + so.sub.3 .fwdarw. h.sub.2 so.sub.4 (5)the net reaction is the decomposition of water into hydrogen and oxygen.
    Type: Grant
    Filed: June 26, 1975
    Date of Patent: July 13, 1976
    Assignee: The United States of America as represented by the United States Energy Research and Development Administration
    Inventor: Robert M. Dreyfuss
  • Patent number: 3966889
    Abstract: Selenium is recovered from combustion waste gas, especially the combustion waste gas evolved from glass melting furnaces by a process in which the waste gas is contacted with an absorbing solution containing an alkali metal sulfite or bisulfite, whereby metallic selenium and selenium compounds are absorbed, the temperature of the waste gas is decreased and the humidity of the waste gas is increased. The treated waste gas in then passed through a moist glass fiber filter which collects the remaining amounts of selenium from the waste gas. The absorbing solution is combined with the solution used to wash the glass fiber filter and the combined solutions are treated with an acid which reduces all of the selenium present in the solution to metallic selenium which precipitates from solution.
    Type: Grant
    Filed: November 14, 1974
    Date of Patent: June 29, 1976
    Assignee: Asahi Glass Co., Ltd.
    Inventors: Hisashi Kakuta, Shigetada Matoba, Kenichi Shimizu, Satoshi Yamashita
  • Patent number: 3954951
    Abstract: Red amorphous selenium is obtained by precipitating selenium from a solution of selenious acid in methanol or ethanol with hydrazine or a soluble salt thereof at a temperature between about -20.degree.C. and the freezing point of the solution.
    Type: Grant
    Filed: August 6, 1974
    Date of Patent: May 4, 1976
    Assignee: Xerox Corporation
    Inventor: David Alan Buckley
  • Patent number: 3933635
    Abstract: Selenium is removed from solution in acidic waste water by treatment of the water with a metallic reducing agent. The invention is particularly effective for removal of selenium from zinc smelter effluent by reaction of the effluent with powdered zinc.
    Type: Grant
    Filed: July 15, 1975
    Date of Patent: January 20, 1976
    Assignee: The United States of America as represented by the Secretary of the Interior
    Inventor: Wayne N. Marchant