From Di- Or Higher Ester Of A Polycarboxylic Acid As Sole Reactant, Or From A Polycarboxylic Acid Or Derivative With A Compound Containing Two Or More Hydroxyl Groups Or Salts Thereof Patents (Class 528/272)
  • Patent number: 11926699
    Abstract: Provided is an aliphatic polyester composition. The aliphatic polyester composition comprises a polybutylene succinate, wherein the proton nuclear magnetic resonance of the aliphatic polyester composition has a first characteristic peak and a second characteristic peak. The first characteristic peak is located between 3.84 ppm and 4.32 ppm, and the second characteristic peak is located between 5.65 ppm and 5.85 ppm. The integral value of the first characteristic peak is set to be 100 and the integral value of the second characteristic peak is less than 0.10. By controlling the integral value of the second characteristic peak in H1-NMR of the aliphatic polyester composition, the aliphatic polyester composition has good appearance and low concentration of carboxylic acid end group and thereby the product value thereof is increased.
    Type: Grant
    Filed: January 18, 2022
    Date of Patent: March 12, 2024
    Assignee: CHANG CHUN PLASTICS CO., LTD.
    Inventors: Jie-Cheng Li, Te-Shun Lin
  • Patent number: 11802202
    Abstract: A modified thermoplastic polyester elastomer and a breathable and waterproof membrane are provided. The modified thermoplastic polyester elastomer is formed from a thermoplastic polyester elastomer, a regenerated polyethylene terephthalate, and a compatibilizer. Based on a total weight of the modified thermoplastic polyester elastomer being 100 phr, a content of the regenerated polyethylene terephthalate is greater than 0 phr and up to 50 phr. Based on a total weight of the thermoplastic polyester elastomer being 100 wt %, the thermoplastic polyester elastomer includes 25 wt % to 75 wt % of hard segments and 25 wt % to 75 wt % of soft segments.
    Type: Grant
    Filed: June 3, 2021
    Date of Patent: October 31, 2023
    Assignee: NAN YA PLASTICS CORPORATION
    Inventors: Te-Chao Liao, Ching-Yao Yuan, Wei-Tang Liao
  • Patent number: 11780150
    Abstract: An oriented film including poly(ethylene-2,5-furandicarboxylate) is produced in a process by preparing a sheet from a poly(ethylene-2,5-furandicarboxylate) resin by heat processing, which sheet has a thickness of at most 2.5 mm; allowing the sheet to cool; and stretching the cooled sheet in at least one direction with a stretch ratio of at least 4/1 at a temperature in the range of 90 to 130° C., yielding an oriented film. The oriented film has a thickness of 1 to 400 ?m and a tensile strength at break of at least 100 MPa.
    Type: Grant
    Filed: February 26, 2021
    Date of Patent: October 10, 2023
    Assignee: Furanix Technologies B.V.
    Inventors: Jeffrey John Kolstad, Jesper Gabriël Van Berkel
  • Patent number: 11739181
    Abstract: This invention relates to a new polyester which is particularly suitable for use in the manufacture of mass-produced articles characterised by excellent mechanical properties, in particular high tensile strength and tensile modulus, associated with a high barrier property against oxygen and carbon dioxide.
    Type: Grant
    Filed: April 20, 2017
    Date of Patent: August 29, 2023
    Assignee: Novamont S.p.A.
    Inventors: Catia Bastioli, Luigi Capuzzi, Tiziana Milizia, Angelos Rallis, Roberto Vallero
  • Patent number: 11560457
    Abstract: The present invention relates to an MDO heat-shrinkable film of a copolymer polyester having excellent thermal resistance. In particular, the present invention provides a copolymer polyester MDO (machine direction orientation) thermoresistant heat-shrinkable film that consists of a copolymer polyester resin including isosorbide and 1,4-cyclohexanedimethanol at an optimized content ratio as a diol component copolymerized with an acid component including terephthalic acid, and having a number average molecular weight of 18,000 g/mol or more, and can be used for labels, cap seals, direct packaging, etc. of various containers due to the high shrink initiation temperature.
    Type: Grant
    Filed: November 24, 2017
    Date of Patent: January 24, 2023
    Inventors: Seol-Hee Lim, Sung-Gi Kim, So-Yeon Kim
  • Patent number: 11555113
    Abstract: A polymer composition is disclosed that comprises a polymer matrix containing at least one thermotropic liquid crystalline polymer and at least one hollow inorganic filler having a dielectric constant of about 3.0 or less at a frequency of 100 MHz wherein the weight ratio of the at least one thermotropic liquid crystalline polymer to the at least one hollow inorganic filler is from about 0.1 to about 10 and wherein the polymer composition exhibits a dielectric constant of about 4 or less and a dissipation factor of about 0.02 or less, as determined at a frequency of 10 GHz.
    Type: Grant
    Filed: August 18, 2020
    Date of Patent: January 17, 2023
    Assignee: Ticona LLC
    Inventors: Young Shin Kim, Darin Grinsteinner
  • Patent number: 11505646
    Abstract: The present invention discloses a method for preparing high-melt-strength polylactide resin by two-step reaction, which comprises the following steps: mixing polylactide resin and GMA to obtain a premix; mixing multifunctional reactive monomer, a peroxide initiator and organic solvent to obtain a monomer mixture; and adding the premix and the monomer mixture into a screw extruder in sections, after melting, blending, extruding, cooling, pelletizing and drying to obtain a high melt strength polylactide resin. The method of the present invention has a simple production process, can be adapted to large-scale industrial production, the graft modification reaction is rapid and controllable, and the obtained product is safe without residue and high in purity. The high-melt-strength polylactide resin has a low melt flow index, high complex viscosity and storage modulus, and is a green polymer material with wide application prospects.
    Type: Grant
    Filed: June 17, 2022
    Date of Patent: November 22, 2022
    Assignee: SOUTH CHINA UNIVERSITY OF TECHNOLOGY
    Inventors: Guangjian He, Weitao Huang, Fulu Chang, Han Yang, Xianwu Cao, Xiaochun Yin
  • Patent number: 11499010
    Abstract: Provided is a polycarbonate of Chemical Formula 1: wherein in Chemical Formula 1: Ar is C6-60 arylene unsubstituted or substituted with C1-10 alkyl; and n and m are each independently an integer from 1 to 50, provided that n+m is 2 or more, and a preparation method thereof.
    Type: Grant
    Filed: August 9, 2019
    Date of Patent: November 15, 2022
    Assignee: LG Chem, Ltd.
    Inventors: Youngwook Son, Young In Yang, Ki Jae Lee, Mooho Hong, Byoungkue Jeon, Young Young Hwang
  • Patent number: 11311491
    Abstract: A method of preparing a pharmaceutical composition having a drug-containing core enclosed by one or more metal oxide materials is provided. The method includes the sequential steps of (a) loading the particles comprising the drug into a reactor, (b) applying a vaporous or gaseous metal precursor to the particles in the reactor, (c) performing one or more pump-purge cycles of the reactor using inert gas, (d) applying a vaporous or gaseous oxidant to the particles in the reactor, and (e) performing one or more pump-purge cycles of the reactor using inert gas. The temperature of the particles does not exceed 35° C. This produces a pharmaceutical composition comprising a drug containing core enclosed by one or more metal oxide materials.
    Type: Grant
    Filed: January 16, 2019
    Date of Patent: April 26, 2022
    Assignee: Applied Materials, Inc.
    Inventors: Colin C. Neikirk, Jonathan Frankel
  • Patent number: 11306175
    Abstract: The present invention relates to a polymer composition comprising a polymeric matrix and particles of an impact modifier within the polymeric matrix, wherein the impact modifier comprises at least one urethane group and the impact modifier is obtainable by reacting in situ within the polymeric matrix a) a polyol comprising a dimer fatty residue; and b) a polyisocyanate. The invention also relates to a method of making the polymer composition.
    Type: Grant
    Filed: November 3, 2016
    Date of Patent: April 19, 2022
    Assignee: Croda International PLC
    Inventors: Angela Leonarda Maria Smits, Johannes Rutger Idsard Knoop
  • Patent number: 11293423
    Abstract: A compressor includes a housing, and an anticorrosive coating covering a surface of the housing. The anticorrosive coating includes a base layer applied on the surface of the housing, and a surface layer applied on the base layer. Both the base layer and the surface layer are organic coatings. Thus, the housing of the compressor is effectively separated from the external environment by means of the two organic coatings, so as to ensure that the compressor is not corroded; moreover, the anticorrosive coating does not contain a metal coating, thereby preventing the problem of the compressor being severely corroded due to an exposed metal coating.
    Type: Grant
    Filed: December 9, 2016
    Date of Patent: April 5, 2022
    Assignee: SHANGHAI HIGHLY ELECTRICAL APPLIANCES CO., LTD.
    Inventors: Zhimin Huang, Jie Li, Zhaodi Fan, Hongsheng Yue, Xiaoxing Jin
  • Patent number: 11286328
    Abstract: The present invention discloses a thermoplastic polyurethane elastomer (TPU), and a preparation method, use and product thereof. The thermoplastic polyurethane elastomer comprises the following components with respect to the total weight of TPU: 22-55 wt % of an aromatic diisocyanate and/or alicyclic diisocyanate; 2-16 wt % of a chain extender; and 30-70 wt % of a polyester polyol. The invention can reduce a TPU injection molding shrinkage to 0.2% or less, and can increase the thermal decomposition temperature to up to 300° C., and can obtain elastomeric materials of different hardnesses, thus having a broad prospect of application in 3D printing methods.
    Type: Grant
    Filed: November 17, 2015
    Date of Patent: March 29, 2022
    Inventors: Jie Yang, Qishan Huang
  • Patent number: 11236213
    Abstract: The present invention provides water-soluble or water-dispersible polyester resins prepared by depolymerizing a terephthalate plastic material in an alcoholysis/glycolysis reaction, and re-polymerizing the product by reacting with a polybasic acid and/or anhydride. The polyester resins of the invention contain 70% to 95% by weight of the terephthalate material, based on the total weight of the composition. The polyester resins of the present invention are useful as dispersants, for example in pigment preparations, and as binders in let-down varnishes, inks, coatings, etc, and as adhesion promoters in aqueous-based inks.
    Type: Grant
    Filed: January 6, 2020
    Date of Patent: February 1, 2022
    Assignee: Sun Chemical Corporation
    Inventors: Jürgen Dieker, Robert Deighton, Kai-Uwe W. Gaudl, Leonora Nurcaj-Dreshaj
  • Patent number: 11236443
    Abstract: A fiber formed from a thermoplastic composition that contains a thermoplastic starch and an aliphatic-aromatic copolyester is provided. The copolyester enhances the strength of the starch-containing fibers and facilitates the ability of the starch to be melt processed. Due to its relatively low melting point, the copolyester may also be extruded with the thermoplastic starch at a temperature low enough to avoid substantial removal of the moisture in the starch. Furthermore, the copolyester is also modified with an alcohol to contain one or more hydroxyalkyl or alkyl terminal groups. By selectively controlling the conditions of the alcoholysis reaction (e.g., alcohol and copolymer concentrations, temperature, etc.), the resulting modified aliphatic-aromatic copolyester may have a relatively low molecular weight.
    Type: Grant
    Filed: May 21, 2013
    Date of Patent: February 1, 2022
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Bo Shi, James H. Wang, Aimin He
  • Patent number: 11214532
    Abstract: Provided is a preparation method for a cyclohexane dimethanol (CHDM), which can have a high trans content through particular conditions, additive addition, or reactant addition, which is controlled in a cyclohexane dicarboxylic acid (CHDA) hydrogenation reaction, and a cyclohexane dimethanol prepared thereby.
    Type: Grant
    Filed: December 21, 2018
    Date of Patent: January 4, 2022
    Assignee: HANWHA SOLUTIONS CORPORATION
    Inventors: Jong Kwon Lee, Ki Don Kim, Eun Jeong Kim, Joo Hee Han, Ho Seong Nam
  • Patent number: 11192079
    Abstract: The present invention relates to the field of high polymer material manufacturing, and discloses an air-isolated continuous feeding system for synthesizing polylactic acid from lactide and a feeding method thereof. The continuous feeding system comprises a raw material bag/box and a raw material collector for collecting and outputting lactide, the raw material bag/box is connected with a shielding gas input pipeline, a discharge pipe is movably inserted into the raw material bag/box, a cyclone separator is connected downstream of the discharge pipe, and a solid substance outlet of the cyclone separator is connected with the raw material collector. According to the invention, deterioration of the lactide raw material incurred by moisture absorption and oxidation is avoided, and the reaction conversion ratio and final product purity are improved. The continuous feeding system is easy to operate, can save manpower and material resources, and is applicable to industrial application.
    Type: Grant
    Filed: December 29, 2020
    Date of Patent: December 7, 2021
    Assignees: Nutrition & Health Research Institute, COFCO Corporation, COFCO (jilin) Bio-Chemical Technology CO., Ltd, Jilin COFCO Biomaterial Co., Ltd, COFCO Biotechnology Co., Ltd.
    Inventors: Yi Tong, Yi Li, Fang Tian, Bo Chen, Tai An, Lida Wu
  • Patent number: 11182032
    Abstract: A touch sensor module according to an embodiment of the present invention includes a touch sensor layer including sensing electrodes and traces branching from the sensing electrodes, a flexible circuit board electrically connected to the traces at one end portion of the touch sensor layer, and a supporting structure commonly and partially covering the flexible circuit board and the touch sensor layer. Damages and delamination of electrodes and wirings included in the flexible circuit board and the touch sensor layer is prevented by the supporting structure.
    Type: Grant
    Filed: December 7, 2020
    Date of Patent: November 23, 2021
    Assignee: DONGWOO FINE-CHEM CO., LTD.
    Inventors: Hye Rim Kwon, Sung Woo Yu, Dong Jin Son, Jin Woo Lee
  • Patent number: 11091632
    Abstract: Biodegradable compositions of polybutylene-succinate (PBS) or polybutylene-succinate-adipate (PBS A) with biobased 3-hydroxybutyrate copolymers are described. In certain embodiments, the copolymer increases the biodegradation rate of the PBS or PBSA. Methods of making the compositions of the invention are also described. The invention also includes articles, films and laminates comprising the compositions.
    Type: Grant
    Filed: November 17, 2016
    Date of Patent: August 17, 2021
    Assignee: CJ CHEILJEDANG CORPORATION
    Inventors: Michael Andrews, Allen R. Padwa, David R. Scarlett
  • Patent number: 11091579
    Abstract: The present disclosure provides an aqueous dispersion. The aqueous dispersion includes a) water; b) a surfactant having at least one ethylenically unsaturated group; and c) polyester particles dispersed in the water. The polyester particles include a water-insoluble polyester having a weight average molecular weight of 20 kiloDaltons or greater, and the polyester particles have an average diameter that is submicron in size. Further, the present disclosure provides a method of making the aqueous dispersion. The method includes a) dissolving a water-insoluble polyester in a water-immiscible solvent to form a polyester solution; b) combining the polyester solution with an aqueous solution including water and a surfactant; and c) removing at least a portion of the water-immiscible solvent to form the aqueous dispersion including polyester particles dispersed in the water.
    Type: Grant
    Filed: June 17, 2019
    Date of Patent: August 17, 2021
    Assignee: 3M Innovative Properties Company
    Inventors: Tianyu Wu, Ying-Yuh Lu, Lin Chen, Jung-Sheng Wu, Ahmed S. Abuelyaman, James D. Hansen, Tianying Jiang, Erick I. Soto Cantu
  • Patent number: 11007758
    Abstract: Disclosed is a biodegradable sheet comprising at least one layer which is a direct contact layer, intended to successfully contact materials, such as liquids, while maintaining the mechanical properties of the sheet and to extend the biodegradable sheet shelf life. The direct contact layer may comprise a hydrophobic polymer selected from poly(epsilon-caprolactone) (PCL) polyhydroxybutyrate (PHB), Polydioxanone (PDO) polyglycolic acid (PGA), polybutylene succinate (PBS), polybutylene succinate adipate (PBSA), poly lactic acid (PLA), polybutylene adipate terphtalate (PBAT), polyhydroxyalkanoates (PHA), such as polyhydroxybutyrates (PHB), polyhydroxyvalerates (PHV), and polyhydroxybutyrate-hydroxyvalerate copolymers (PHBV) or any mixture thereof. The biodegradable sheet may further comprise surface treated nanoclay particles, PVOH grafted with a crosslinker and PBS or PBSA The first hydrophobic polymer is present in said at least one layer in an amount of about 30% w/w.
    Type: Grant
    Filed: April 27, 2020
    Date of Patent: May 18, 2021
    Assignee: Tipa Corp. Ltd
    Inventors: Daphna Nissenbaum, Tal Neuman, Dori Pelled, Shai Garty, Nili Konieczny
  • Patent number: 11001727
    Abstract: The present disclosure is directed to marking compositions that are derived from environmentally friendly, biodegradable, and sustainable resources. Such compositions may be formulated in to writing and/or drawing instruments such as crayons. In various embodiments, the marking compositions include one or more of a structural component, a stiffening and/or laydown component, and a colorant. For instance, the structural component may be an ester wax composed of a diol and diacid, such as where the diols and diacids contain about 2 to about 14 carbon atoms each, such as where the structural component is present in an amount of from about 10% by weight to about 90% by weight, such as about 20% to about 80%, including about 60% of the composition. Additionally, the stiffening and/or lay down component may be a bifunctional fatty acid, such as stearic acid, which may be included in the composition, such as a stiffening agent as well as to enhance smoothness of laydown.
    Type: Grant
    Filed: October 26, 2017
    Date of Patent: May 11, 2021
    Assignees: Danimer Bioplastics, Inc., Tecniq Holdings, LLC
    Inventors: Rob Falken, Adam Johnson, Rachelle Arnold, Phillip Van Trump
  • Patent number: 10927477
    Abstract: A process of forming a fiber comprised of a plurality of bio-char particles, comprising: combining a portion of a polymer with a hemp derivative, said hemp derivative selected form a hemp carbon made by pyrolyzing a quantity of hemp stalk at between 1100-1500° C. to create a char; adding the char to a milling vessel and milling the char for a period of between 1 to 16 hours, and a full spectrum hemp extract, or combinations thereof, wherein the polymer and hemp derivative are extruded to form a fiber.
    Type: Grant
    Filed: April 27, 2020
    Date of Patent: February 23, 2021
    Assignees: Thomas Jefferson University, Ecofibre USA Inc.
    Inventors: Mark Sunderland, Jeffrey William Bruner, Lee Benjamin Williams
  • Patent number: 10894859
    Abstract: A copolymerized polyester resin containing a unit (A) represented by the following formula (1), a diol unit (B), and a unit (C) derived from a dicarboxylic acid or an ester-forming derivative of the dicarboxylic acid, wherein a content of the unit (A) based on total units of the copolymerized polyester resin is 10 to 95 mol %, and the copolymerized polyester resin satisfies the following conditions (1) to (3): (1) a glass transition temperature of the copolymerized polyester resin is 90° C. or higher; (2) an amount of heat generated by the copolymerized polyester resin at cooling crystallization is 5 J/g or less; and (3) an absolute value of photoelastic coefficient of the copolymerized polyester resin is 40×10?12 Pa?1 or less: wherein R1 is a hydrogen atom, CH3, or C2H5, R2 and R3 are each independently a hydrogen atom or CH3, and n is 0 or 1.
    Type: Grant
    Filed: September 27, 2017
    Date of Patent: January 19, 2021
    Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Eiichi Honda, Yasuaki Yoshimura, Keita Noguchi, Yuichiro Satake, Takashi Motoi
  • Patent number: 10759972
    Abstract: The adhesive tape includes: a resin layer that is formed by applying resin coating, the resin coating containing a resin having an acid number of 50 mg/g or more and 130 mg/g or less, and at least one type of cross-linking agent selected from between an epoxy-based cross-linking agent and a metal chelate cross-linking agent; and an adhesive layer that is laminated on or above the resin layer, and is formed by applying adhesive coating, the adhesive coating containing a resin including a hydroxyl group, and a metal chelate compound.
    Type: Grant
    Filed: February 24, 2016
    Date of Patent: September 1, 2020
    Assignee: MAXELL HOLDINGS, LTD.
    Inventors: Masanao Shibuya, Yusuke Kato, Takayuki Shimoda, Katsumi Hashimoto, Takahiro Sakai
  • Patent number: 10719024
    Abstract: An embodiment of the present invention relates to a method for producing a binder resin, from which a toner having excellent low-temperature fusing property, roller release properties, and pulverization properties, is obtained, a binder resin, and a toner for development of electrostatic images including the binder resin.
    Type: Grant
    Filed: August 28, 2018
    Date of Patent: July 21, 2020
    Assignee: KAO CORPORATION
    Inventors: Norihiro Fukuri, Takashi Kubo
  • Patent number: 10696787
    Abstract: An object of the present invention is to provide a liquid crystal polyester resin having low-temperature processability and improved mechanical properties. The present invention relates to a liquid crystal polyester resin comprising specific repeating units and having a crystal melting temperature of less than 210° C. as measured with a differential scanning calorimeter.
    Type: Grant
    Filed: August 20, 2018
    Date of Patent: June 30, 2020
    Assignee: UENO FINE CHEMICALS INDUSTRY, LTD.
    Inventors: Shogo Takasuka, Hisanari Fujiwara, Tetsuya Yamashita
  • Patent number: 10696816
    Abstract: The present invention addresses the problem of providing a polyester resin composition for reflective materials which gives a reflective material having a high reflectance. The polyester resin composition for reflective materials comprises: a polyester resin (A) comprising an alicyclic dicarboxylic acid ingredient unit (a1) and an aliphatic diol ingredient unit (b1); and a white pigment (B). The amount of the alicyclic dicarboxylic acid ingredient unit (a1) is 50 mol % or more of the amount of all the dicarboxylic acid ingredient units (a) in the polyester resin (A), and the amount of the aliphatic diol ingredient unit (b1) is 50 mol % or more of the amount of all the diol ingredient units (b) in the polyester resin (A). The alicyclic dicarboxylic acid ingredient unit (a1) comprises the cis and trans forms of cis-trans isomers, the proportion of the cis form determined by NMR being 20 mol % or higher.
    Type: Grant
    Filed: March 26, 2015
    Date of Patent: June 30, 2020
    Assignee: MITSUI CHEMICALS, INC.
    Inventors: Kaoru Ohshimizu, Hideto Ogasawara, Hiroki Ebata, Takashi Hama, Fumio Kageyama, Shintaro Mitsunaga, Nobuhiro Takizawa, Akinori Amano
  • Patent number: 10685763
    Abstract: A conductive polymer composite is disclosed. The composite comprises a thermoplastic polymer; carbon nanotubes in an amount ranging from 2% to about 40% by weight, relative to the total weight of the conductive polymer composite; and a plurality of graphitic particles in an amount ranging from about 2% to about 50% by weight, relative to the total weight of the conductive polymer composite.
    Type: Grant
    Filed: January 19, 2016
    Date of Patent: June 16, 2020
    Assignee: XEROX CORPORATION
    Inventors: Rachel Prestayko, Sarah J. Vella, Carolyn Moorlag, Barkev Keoshkerian
  • Patent number: 10683400
    Abstract: This invention provides compositions and methods for reversible ionic crosslinking in polymers, providing tunability of polymer mechanical properties. Some variations provide a polymer composition comprising: a polymer containing a plurality of ionic species disposed along the chain backbone of the polymer, wherein the plurality of ionic species has an ionic charge polarity that is negative or positive; a redox reagent; and a reversible crosslinking agent capable of changing from a first oxidation state to a second oxidation state when in the presence of the redox reagent. The different oxidation states are associated with different coordination numbers between the reversible crosslinking agent and the ionic species contained in the polymer. This difference provides reversible ionic crosslinking. The polymer may be selected from polyurethanes (including segmented and non-segmented polyurethanes), polyacrylates, or polyamides, for example.
    Type: Grant
    Filed: October 24, 2017
    Date of Patent: June 16, 2020
    Assignee: HRL Laboratories, LLC
    Inventors: April R. Rodriguez, Ashley M. Nelson, Shanying Cui, Andrew P. Nowak, Adam F. Gross
  • Patent number: 10670981
    Abstract: To provide a toner for electrophotography and a binder resin, exhibiting an excellent fog suppression capability. A toner for electrophotography and a binder resin each containing a resin A having at least a polyester moiety obtained through polycondensation of an alcohol component, a carboxylic acid component, and a polyhydroxyamine compound represented by the formula (1) in an amount of 0.01% by mass or more and 5.0% by mass or less based on the total amount of all the monomer components of the resin A.
    Type: Grant
    Filed: February 9, 2017
    Date of Patent: June 2, 2020
    Assignee: KAO CORPORATION
    Inventors: Takashi Kubo, Kota Ijichi
  • Patent number: 10604620
    Abstract: A method and an apparatus for solid-state polycondensation of polyesters, preferably polyethylene terephthalate and/or copolymers thereof. The method and apparatus are both characterized by a solid-state polycondensation being performed with polyester prepolymer particles in a reaction chamber in which an absolute pressure is in the range from 10 mbar to 200 mbar, and a process gas flow in the range of an R-value of 0.005 to 0.05. The polycondensation is carried out over a time of from 2 to 30 hours and at a temperature of from 180° C. to 5° below a crystalline melting point of the polyester prepolymer particles in order to achieve an intrinsic viscosity of from 0.70 to 0.95 dl/g. The R value is defined as a ratio of an hourly amount of process gas (in kg) flowing through the reaction space to an hourly amount of polymer (in kg) flowing through the reaction space: R = m ? ( gas ) ? / ? h m ? ( polymer ) ? / ? h .
    Type: Grant
    Filed: December 18, 2012
    Date of Patent: March 31, 2020
    Assignee: Polymetrix AG
    Inventor: Andreas Christel
  • Patent number: 10556388
    Abstract: The present invention is generally directed to prepreg composites, typically in the form of unidirectional tapes, which contain at least one reinforcing fiber and a thermoplastic polyester matrix. The prepreg composites can be thermally bonded to a wood-containing material in order to improve the structural performance of the material without requiring adhesives. The prepreg composite of the present invention can be applied to a wide range of wood substrates, including various hardwoods, softwoods, and engineered wood composites.
    Type: Grant
    Filed: April 22, 2015
    Date of Patent: February 11, 2020
    Assignee: Eastman Chemical Company
    Inventors: Mark Allan Treece, John Thomas Hofmann, Kendrick Casey Halsey
  • Patent number: 10548769
    Abstract: Provided is a glaucoma valve, a casing for containing a glaucoma valve and a glaucoma drainage device including the glaucoma valve and/or the casing. The valve includes a flow channel having an inlet and an outlet and a valve member connected to the outlet of the flow channel. The valve member may be formed from a degradable polymer or a combination of degradable polymer and non-degradable polymer. The valve may have a first flow channel, the interior of which may be coated with a degradable polymer, such that in use, the polymer degrades to allow a greater flow of fluid through the flow channel. The valve may include a second flow channel, which may be arranged in parallel to the first flow channel. The casing may be formed from a degradable polymer, such as a biodegradable polymer.
    Type: Grant
    Filed: August 12, 2011
    Date of Patent: February 4, 2020
    Assignees: NANYANG TECHNOLOGICAL UNIVERSITY, SINGAPORE HEALTH SERVICES PTE LTD.
    Inventors: Subramanian Venkatraman, Lei Shang, Yin Chiang Freddy Boey, Tina Wong
  • Patent number: 10528790
    Abstract: Compositions, films, collection devices, apparatuses, kits and methods related to biologic analyte collection and analysis include thin films of modified polycaprolactone. Methods of production and use thereof are described herein. The films, compositions, collection devices, kits and methods can be used for collection of fingerprints for both image capture and nucleic acid extraction and analysis.
    Type: Grant
    Filed: July 2, 2019
    Date of Patent: January 7, 2020
    Assignee: Diomics Corporation
    Inventors: Beverly Lynn Wolgast, John F. Steel, Thomas J. Kindt, Ryan B. Lamer
  • Patent number: 10519343
    Abstract: Provided herein are compositions having a good balance between the curing speed, transparency, tackiness and/or melt viscosity thereof. In one aspect, there are provided compositions containing nano-particulate filler and the use thereof in the preparation of a variety of electronic components, e.g., three-dimensional integrated circuits. In certain aspects, there are provided three-dimensional integrated circuits prepared employing invention compositions (i.e., compositions containing nano-particulate filler), as well as methods for preparing such compositions, and the resulting three-dimensional integrated circuits. In certain aspects, there are also provided methods for improving the curing speed, transparency, tackiness and/or melt viscosity of pre-applied underfill compositions. In certain aspects, there are also provided pre-applied underfill compositions with improved processability.
    Type: Grant
    Filed: June 30, 2016
    Date of Patent: December 31, 2019
    Assignee: HENKEL IP & HOLDING GMBH
    Inventor: Qiaohong Huang
  • Patent number: 10433543
    Abstract: A multi-layer bioactive and biodegradable film. The multi-layer film includes one or more bioactive compounds or microorganisms for promoting growth and health of a plant, the bioactive compounds or microorganisms contained between layers of the film, wherein each one of the layers comprises about 60% to about 75% (m/m) polyhydroxyalkanoate. The bioactive compounds or microorganisms may include any one of or a combination of: a metabolite, an anti-microbial compound, an enzyme, a live microorganism, a fertilizer, a plant growth hormone, a preservative, a pesticide or an herbicide. Release of one or more bioactive compounds may be achieved in a timed and controlled manner.
    Type: Grant
    Filed: April 14, 2017
    Date of Patent: October 8, 2019
    Assignee: TerraVerdae BioWorks Inc.
    Inventors: William Bardosh, Ryan Richard McKenzie, Tizazu Mekonnen, Manoj Gokul Nerkar, Misha Miazga-Rodriguez
  • Patent number: 10420209
    Abstract: The polyester sheet in accordance with an aspect of the present invention contains crystals of polyester which is a polycondensate of polyvalent carboxylic acid and polyalcohol. The polyester sheet contains nano-oriented crystals which contain crystals of polyester in each of which a polymer chain is highly oriented and each of which has a crystal size of 50 nm or less. A heatproof temperature of the polyester sheet is higher than a temperature that is lower than an equilibrium melting point of the polyester by 80° C., and a melting point of the polyester sheet is higher than a temperature that is lower than the equilibrium melting point of the polyester by 40° C.
    Type: Grant
    Filed: August 24, 2015
    Date of Patent: September 17, 2019
    Assignee: HIROSHIMA UNIVERSITY
    Inventors: Masamichi Hikosaka, Kiyoka Okada, Yoshitaka Tanaka
  • Patent number: 10346671
    Abstract: Compositions, films, collection devices, apparatuses, kits and methods related to biologic analyte collection and analysis include thin films of modified polycaprolactone. Methods of production and use thereof are described herein. The films, compositions, collection devices, kits and methods can be used for collection of fingerprints for both image capture and nucleic acid extraction and analysis.
    Type: Grant
    Filed: January 23, 2015
    Date of Patent: July 9, 2019
    Assignee: Diomics Corporation
    Inventors: Beverly Lynn Wolgast, John F. Steel, Thomas J. Kindt, Ryan B. Lamer
  • Patent number: 10344110
    Abstract: Disclosed herein are embodiments of methods for making and using functionalized forms of polydicyclopentadiene polymers. The disclosed polymers and methods enable a greater range of uses than the unmodified polydicyclopentadiene, which is currently used industrially. In addition, the presence of the functional groups contemplated by the disclosed compounds and formulae allow for the control of the polymer surface energy, and also enables the use of reversible chemical crosslinks, which permits recycling of the material.
    Type: Grant
    Filed: August 17, 2018
    Date of Patent: July 9, 2019
    Assignee: UVic Industry Partnerships Inc.
    Inventors: Jeremy E. Wulff, Jun Chen, Matthew G. Moffitt, Fraser P. Burns, Tyler J. Cuthbert, Chang Liu, Tong Li
  • Patent number: 10246560
    Abstract: Embodiments of the invention concern copolymers and nanoparticles for use as delivery agents for one or more agents for therapy for a medical condition of humans and animals. Some of embodiments of the invention provide new reagents for biomedical research in cell culture, animal models and plants, for example. The copolymers comprise PLGA and PEI and, in some embodiments, also comprise 1-(3-aminopropyl)-4-methylpiperazine (APMP), Fc binding peptide and/or antibody. In certain embodiments, APMP-PLGA-PEI, Fc binding peptide/antibody-PLGA-PEI or Fc binding peptide/antibody-AP-MP-PLGA-PEI nanoparticles comprising one or more therapeutic agents are delivered to an individual in need thereof or used for biomedical research in cell cultures, animal models and plants.
    Type: Grant
    Filed: August 13, 2014
    Date of Patent: April 2, 2019
    Assignee: Baylor College of Medicine
    Inventors: Jian-Ming Lu, Qizhi Yao, Changyi Chen
  • Patent number: 10239267
    Abstract: Injection stretch blow molding process for preparing polyolefin containers, comprising the following steps: 1) preparing a preform by injection molding a polyolefin composition comprising a polymer (A) selected from ethylene polymers, propylene polymers and mixtures thereof, and a heat absorber (B); 2) supplying heat to reheat the preform prepared in step 1) and stretch blow molding said preform; wherein the heat absorber (B) is selected from phosphates, condensed phosphates, phosphites, and mixed hydroxide/phosphate oxanion compounds of Copper (Cu), Calcium (Ca), Tin (Sn) and/or Iron (Fe).
    Type: Grant
    Filed: October 20, 2011
    Date of Patent: March 26, 2019
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Mike Rogers, Anja Gottschalk
  • Patent number: 10201632
    Abstract: Biodegradable, cross-linked polymer particle embolics and methods of making the same are described. The particle embolics can be used as embolization agents.
    Type: Grant
    Filed: September 28, 2017
    Date of Patent: February 12, 2019
    Assignee: Terumo Corporation
    Inventors: Gloria Hincapie, Xinping Wu, Yue Wu, Gregory M. Cruise
  • Patent number: 10179891
    Abstract: The present invention relates to the use of branched polyesters obtainable by polycondensation of citric acid with at least one polyalcohol, and optionally with polycarboxylic acid component as additive in washing compositions, cleaners, detergents or a formulation for water treatment and to mixtures comprising such branched polyesters. The invention further relates to the use of hydrophobically modified branched polyesters, and to the method for cleaning, washing or water treatment using such branched polyesters.
    Type: Grant
    Filed: July 25, 2013
    Date of Patent: January 15, 2019
    Assignee: BASF SE
    Inventors: Jürgen Detering, Monika Haberecht, Anna Müller-Cristadoro, Heike Weber
  • Patent number: 10065405
    Abstract: This disclosure relates to a film for a tire inner liner film that may exhibit uniform excellent physical properties over all directions when applied to a tire, and may secure excellent durability and fatigue resistance in a tire manufacturing process or in an automobile running process, a method for manufacturing the film for a tire inner liner, a pneumatic tire using the tire inner liner film, and a method for manufacturing the pneumatic tire using the tire inner liner film.
    Type: Grant
    Filed: March 8, 2013
    Date of Patent: September 4, 2018
    Assignee: KOLON INDUSTRIES, INC.
    Inventors: Yun-Jo Kim, Si-Min Kim, Dong-Jin Kim, Il Chung, Dong-Hyeon Choi
  • Patent number: 10018757
    Abstract: A multilayer polymeric reflector is provided which comprises: a) a plurality of first optical layers, each first optical layer comprising a polyester having terephthalate comonomer units and ethylene glycol comonomer units, the polyester having a glass transition temperature, where each first optical layer is oriented, and b) a plurality of second optical layers disposed in a repeating sequence with the plurality of first optical layers, each second optical layer comprising a blend of polymethyl methacrylate (PMMA) and polyvinylidene fluoride (PVDF), where the blend has a glass transition temperature less than the glass transition temperature of the polyester comprising the first optical layers, and where the amount of PVDF in the PMMA/PVDF blend is greater than and not equal to about 40% and not more than about 65%. Articles comprising the multilayer polymeric reflector are also provided.
    Type: Grant
    Filed: August 2, 2017
    Date of Patent: July 10, 2018
    Assignee: 3M INNOVATIVE PROPERTIES COMPANY
    Inventor: Huiwen Tai
  • Patent number: 10017597
    Abstract: A substantially gel-free and substantially linear biodegradable polyester obtainable by reaction with a radical initiator starting from a precursor polyester provided with an unsaturated chain terminator, wherein the terminator has the formula: T-(CH2)n-CH?CH2, wherein “T” is selected from hydroxylic, carboxylic, amine, amide or ester group, and “n” is an integer comprised between 0 and 13. The content of the unsaturated chain terminator is between 0.01 and less than 1% by moles with respect to the moles of repetitive units of the polyester precursor; and the content of the radical initiator is less than 0.08 wt % with respect to the quantity of the precursor polyester.
    Type: Grant
    Filed: September 24, 2010
    Date of Patent: July 10, 2018
    Assignee: NOVAMONT S.P.A.
    Inventors: Catia Bastioli, Luigi Capuzzi
  • Patent number: 9976030
    Abstract: A resin composition contains a polycarbonate resin, a reaction product of a glycidyl-group-containing polyethylene copolymer with a polyethylene terephthalate resin, a polyethylene terephthalate resin that has not reacted with the glycidyl-group-containing polyethylene copolymer, an organic phosphorus flame retardant, and a flame-retardant anti-drip agent, wherein the amount of the polyethylene terephthalate resin in the reaction product is approximately not less than 3 mass % relative to the amount of the whole reaction product.
    Type: Grant
    Filed: August 3, 2016
    Date of Patent: May 22, 2018
    Assignee: FUJI XEROX CO., LTD.
    Inventor: Akira Imada
  • Patent number: 9938367
    Abstract: Biodegradable, cross-linked polymer particle embolics and methods of making the same are described. The particle embolics can be used as embolization agents.
    Type: Grant
    Filed: June 22, 2017
    Date of Patent: April 10, 2018
    Assignee: Terumo Corporation
    Inventors: Gregory M. Cruise, Gloria Hincapie, Clayton Harris
  • Patent number: 9897921
    Abstract: This invention relates to a composition comprising mineral spirits in combination with an alcohol or diisopropylbenzene or both, and methods directed to the preparation and use of this composition. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
    Type: Grant
    Filed: August 21, 2015
    Date of Patent: February 20, 2018
    Assignee: NSX Operating Co. LLC
    Inventor: Jon-Eric Bonney
  • Patent number: 9896539
    Abstract: A method for synthesizing poly(butylene adipate-co-terephthalate) by combination of melt and solid state polycondensation using an organic guanidine as a main catalyst. The ternary catalyst system includes a main catalyst, a first cocatalyst, and a second cocatalyst. The main catalyst is organic guanidine; the first cocatalyst is titanate ester or zirconate ester; and the second cocatalyst is metallic oxide. The method includes: 1) adding 1,4-butanediol (BDO), adipic acid (AA), terephthalic acid (TA), and a ternary catalyst system to a reaction still; conducting an oligo-polycondensation to yield a oligomer having the weight average molecular weight (Mw) of between 3.0×103 and 4.0×103; allowing the oligomer to perform a melt polycondensation (MP) to yield a prepolymer with medium Mw of between 1.5×104 and 3.0×104; and 2) crushing the solid prepolymer into granules of 30-40 meshes, and then allowing the granules to undergo solid state polycondensation to yield the final PBAT product.
    Type: Grant
    Filed: September 12, 2016
    Date of Patent: February 20, 2018
    Assignee: NANJING UNIVERSITY
    Inventors: Hong Li, Quanxing Zhang, Xiangqian Sun, Yunlong Xu, Wei Huang, Aimin Li