Phosphorus Containing Acid Patents (Class 536/34)
  • Patent number: 11834776
    Abstract: A process is disclosed for modifying citrus fiber. Citrus fiber is obtained having a c* close packing concentration value of less than 3.8 w %, anhydrous basis. The citrus fiber can have a viscosity of at least 1000 mPa·s, wherein said citrus fiber is dispersed in standardized water at a mixing speed of from 800 rpm to 1000 rpm, to a 3 w/w % citrus fiber/standardized water solution, and wherein said viscosity is measured at a shear rate of 5 s-1 at 20 C. Citrus fiber can be obtained having a CIELAB L* value of at least 90. The citrus fiber can be used in food products, feed products, beverages, personal care products, pharmaceutical products or detergent products.
    Type: Grant
    Filed: February 6, 2018
    Date of Patent: December 5, 2023
    Assignee: Cargill, Incorporated
    Inventors: Todd Walter Gusek, Jacques Andre Christian Mazoyer, David Hiram Reeder, Joel Rene Pierre Wallecan
  • Patent number: 11623967
    Abstract: A process is disclosed for obtaining citrus fiber from citrus pulp. Citrus fiber is obtained having a c* close packing concentration value of less than 3.8. The citrus fiber can be obtained having a viscosity of at least 1000 mPa.s, wherein said citrus fiber is dispersed in standardized water at a mixing speed of from 800 rpm to 1000 rpm, to a 3 w/w% citrus fiber/standardized water solution, and wherein said viscosity is measured at a shear rate of 5 s-1 at 20° C. Citrus fiber can be obtained having a CIELAB L* value of at least 90. The citrus fiber can be used in food products, feed products, beverages, personal care products, pharmaceutical products or detergent products.
    Type: Grant
    Filed: January 29, 2018
    Date of Patent: April 11, 2023
    Assignee: Cargill, Incorporated
    Inventors: Todd Walter Gusek, Jacques Andre Christian Mazoyer, David Hiram Reeder, Joel Rene Pierre Wallecan
  • Patent number: 7943761
    Abstract: The present invention discloses a cellulose based optical film material with the following structure: wherein R1 is —H or —C(O)R4, R4 is alkyl or aryl; R2 is —C(O)R5, R5 is alkyl or aryl; R3 comprises one of the group consisting of: phosphinate based group, phosphonate based group, phosphonamide based group, phosphate based group, phosphoramide based group, carbamate based group, carbonate based group, and ester based group. Further, this invention also discloses a method for forming the cellulose based optical film material.
    Type: Grant
    Filed: October 19, 2006
    Date of Patent: May 17, 2011
    Assignee: National Taiwan Normal University
    Inventor: Chien-Tien Chen
  • Patent number: 7803937
    Abstract: This invention relates to cellulose II phosphate which may be partly carbamidated, and also to a metal-adsorbing material making use of the same. This cellulose II phosphate efficiently adsorbs metal ions in a solution, and can be used as a metal-adsorbing material and in a metal-adsorbing system.
    Type: Grant
    Filed: October 20, 2004
    Date of Patent: September 28, 2010
    Assignee: Kowa Co., Ltd.
    Inventor: Katsumi Yabusaki
  • Patent number: 6579977
    Abstract: A process is disclosed for producing biosorbents by phosphorylation of cellulose-containing materials with phosphoric acid or ammonium phosphate in the presence of urea. Also disclosed are biosorbents with particular good use properties. Biosorbents of this type are used, in particular, for removing heavy metals from aqueous solutions. Proceeding from the disadvantages of the known prior art, purification costs of resultant raw products should be lowered and the formation of unwanted soluble organic polymer phosphates as by-products should be prevented. The biosorbents should have an improved mechanical strength and very good use properties. The disclosed biosorbents contain 5-10 % phosphorus and 1-4 % nitrogen in the form of carbamide groups. The synthesis mixture is mixed with elementary sulphur before starting the reaction in order to produce biosorbents with an increased mechanical strength. The proposed procedure allows reducing the otherwise customary reaction temperatures by about 40° C.
    Type: Grant
    Filed: May 31, 2000
    Date of Patent: June 17, 2003
    Assignee: EISU Innovative Gesellschaft fur Technik und Umweltschutz mbH
    Inventors: Friedemann Pieschel, Ekkehard Lange, Juan Camacho, Christine Fieseler, Hendrik Ikier
  • Patent number: 6075139
    Abstract: Sucrose ester and ether products, useful as food or beverage bulking agents, reduced calorie sweeteners, fat replacement agents, stabilizing agents, thickening agents and emulsifying agents; adhesives; biodegradable plastics and films; sizing agents for paper and textiles; ethical pharmaceuticals and new fibers are prepared by using a two-phase reaction system in which sucrose is dissolved in an alkaline, aqueous solution and an acidic reagent such as a bifunctional acid dichloride or epoxide is added to the sucrose in a water-immiscible organic solvent. Several types of products are produced: water-insoluble sucrose ester (ether) copolymers; water-soluble sucrose ester (ether) copolymers; sucrose ester (ether) dimers; and intramolecular, cyclic sucrose esters (ethers). These products can be further varied by using different kinds of acid dichlorides or epoxides that contain different kinds of functional groups.
    Type: Grant
    Filed: July 24, 1996
    Date of Patent: June 13, 2000
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: John F. Robyt, Rupendra Mukerjea
  • Patent number: 5093489
    Abstract: A modified cellulose and/or chitin for biocompatible dialysis membranes having a structure represented by the formula ##STR1## wherein Cell is cellulose or chitin, in each case without hydroxyl groups, s=3 in the case of cellulose and s=2 in the case of chitin, R' is CH.sub.3 and/or C.sub.2 H.sub.5 and/or C.sub.3 H.sub.7, X denotes specified functional groups, R" is H or R, Z corresponds to the following groups of atoms: SR", SO.sub.3 H and salts thereof, SO-R, SONR".sub.2, SO.sub.2 -R, SO.sub.2 NR".sub.2, SO.sub.2 H and salts thereof, F, Cl, Br, I, NR".sub.2, PR".sub.2, PO.sub.3 H.sub.2 and salts thereof, PO.sub.2 H(OR), PO(OR).sub.2, PO.sub.2 HR" and salts thereof, POR"(OR) and POR".sub.2, x+t=0.75 to 2.85, t=0 to 2.85, x=0 to 2.85, and z=0.01 to 0.45. A process for preparation of the cellulose and/or chitin derivatives is also disclosed.
    Type: Grant
    Filed: October 19, 1990
    Date of Patent: March 3, 1992
    Assignee: Akzo N.V.
    Inventor: Michael Diamantoglou
  • Patent number: 5093488
    Abstract: A modified cellulose and/or chitin for biocompatible dialysis membranes having a structure represented by the formula ##STR1## wherein cell is cellulose or chitin, in each case without hydroxyl groups, s=3 in the case of cellulose and s=2 in the case of chitin, R' is CH.sub.3 and/or C.sub.2 H.sub.5 and/or C.sub.3 H.sub.7, X denotes specified functional groups, R" is H or R, R"' denotes R, x+t=0.75 to 2.85, t=0 to 2.85, x=0 to 2.85, and r=0 to 1. A process for preparation of the cellulose and/or chitin derivatives is also disclosed.
    Type: Grant
    Filed: October 19, 1990
    Date of Patent: March 3, 1992
    Assignee: Akzo N.V.
    Inventor: Michael Diamantoglou
  • Patent number: 5093486
    Abstract: A modified cellulose and/or chitin for biocompatible dialysis membranes having a structure represented by the formula ##STR1## wherein cell is unmodified cellulose or chitin, in each case without hydroxyl groups, s=3 in the case of cellulose and s=2 in the case of chitin, R' is CH.sub.3 and/or C.sub.2 H.sub.5 and/or C.sub.3 H.sub.7, X denotes specified functional groups, m=0.75 to 2.85, and x=0.005 to 2.10. A process for preparation of the cellulose and/or chitin derivatives is also disclosed.
    Type: Grant
    Filed: October 19, 1990
    Date of Patent: March 3, 1992
    Assignee: Akzo N.V.
    Inventor: Michael Diamantoglou
  • Patent number: 4685909
    Abstract: Absorbent articles containing both pH control agents and substantially water-insoluble, highly neutralized hydrogel material as a fluid-absorbing polymer are disclosed. By placing pH control agents and hydrogel in distinct discrete zones within the article, absorbent products such as diapers can be realized which are highly effective for absorbing discharged body fluids and which also serve to prevent or reduce diaper rash.
    Type: Grant
    Filed: August 22, 1986
    Date of Patent: August 11, 1987
    Assignee: The Procter & Gamble Company
    Inventors: Ronald W. Berg, Robert L. Stewart
  • Patent number: 4260738
    Abstract: Starch ether derivatives are prepared by reacting a starch base with N-(2-haloethyl)iminobis(methylene)diphosphonic acid or with a N-(alkyl)-N-(2-haloethyl)aminomethylphosphonic acid. The derivatives contain aminophosphonic acid groups (or their salts) as zwitterion substituents which consist of either one or two anionic methylene phosphonic acid groups bound to a cationic nitrogen. Their cationic or anionic characteristics may be increased by introducing suitable cationic or anionic groups either by simultaneous reaction with the aminophosphonic acid reagent or by consecutive reaction either prior to or subsequent to the aminophosphonic acid reaction. They are especially useful as pigment retention aids in paper making processes.
    Type: Grant
    Filed: January 10, 1980
    Date of Patent: April 7, 1981
    Assignee: National Starch and Chemical Corporation
    Inventor: Martin M. Tessler
  • Patent number: 4256111
    Abstract: Chemically modified cellulose fibers such as those which have been subjected to phosphorylation or carboxymethylation or to polymer grafting-hydrolysis are refined in the presence of water, centrifuged to remove unbound water and extruded into filaments. The individual fibers are identifiable within the filaments and are generally aligned parallel to the filament axis. Certain embodiments of the filaments are highly absorbent, have fast wicking rates, and may be self-bonded to form integral nonwoven webs for use in disposable diapers, sanitary products, wipers and the like.
    Type: Grant
    Filed: October 1, 1973
    Date of Patent: March 17, 1981
    Assignee: Kimberly-Clark Corporation
    Inventor: Frederick O. Lassen
  • Patent number: 4150021
    Abstract: Dyes of the formula ##STR1## are disclosed which are useful in dyeings where the phosphonic acid group serves both as a water-solubilizing group and as a group capable of reacting to bond covalently with the fiber to be dyed. Application of the dyes to cellulose results in reactive dyeing by immobilization of the dye as a cellulose phosphonate ester. The dye substituent is a chromophore, e.g. an anthraquinone or azo chromophore, while R may be hydrogen or lower alkyl.
    Type: Grant
    Filed: February 8, 1978
    Date of Patent: April 17, 1979
    Assignee: Burlington Industries, Inc.
    Inventors: Ronald Swidler, William A. Sanderson